Crystal templating through liquid-liquid phase separation.

نویسندگان

  • Joanna Mosses
  • David A Turton
  • Leo Lue
  • Jan Sefcik
  • Klaas Wynne
چکیده

Controlled induction of crystal nucleation is a highly desirable but elusive goal. Attempts to speed up crystallization, such as high super saturation or working near a liquid-liquid critical point, always led to irregular and uncontrollable crystal growth. Here, we show that under highly nonequilibrium conditions of spinodal decomposition, water crystals grow as thin wires in a template-less formation of "Haareis". This suggests that such nonequilibrium conditions may be employed more widely as mechanisms for crystal growth control.

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عنوان ژورنال:
  • Chemical communications

دوره 51 6  شماره 

صفحات  -

تاریخ انتشار 2015